Martin Redrado claimed credit for bringing Argentina monetary stability for the first time in 30 years, but said President Cristina Fernandez had disregarded this achievement while unconstitutionally ordering his removal.
"I went through all the institutional steps," he said. "Unfortunately, the government didn't do the same and disregarded the independence of the Central Bank."
The president ordered Redrado fired this month after he refused her decree to make the bank's reserves available for paying off $6.6 billion in national debt and also for spending of undefined "excess reserves" for other purposes.
The Central Bank has about $48 billion in reserves, and some analysts said the decree's wording would enable the president to unilaterally use more of it for other spending.
A judge blocked Fernandez's decree and a congressional panel had been considering whether to approve or reject it.
Fernandez had urged the panel to rule quickly to resolve the crisis.
Her Cabinet chief refused to accept Redrado's resignation Friday, in effect saying the bank president can't quit because he has already been fired.
"For us, the resignation doesn't exist," Anibal Fernandez told the C5N news channel, adding that the government would wait for the congressional panel's decision.