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Peter Moylan (6-2) won with a scoreless sixth after taking over for starter Mike Minor, who surrendered four runs and seven hits in five-plus innings.
Carpenter allowed more than three earned runs for the first time since July 3, a span of 12 starts.
"I felt good. My stuff was good," he said. "It was bad timing to have an inning like that."
La Russa's unorthodox lineup, revived for the series in Atlanta in hopes of sparking his slumping team, appeared to backfire when Carpenter, batting just .098 (6 for 61), came up in the second with two outs and two runners aboard.
Not so fast. Carpenter lined a single to left to put the Cardinals ahead.
After the Braves tied it on Nate McLouth's long homer in the bottom half, Holliday hit a drive over the center-field wall for his 26th homer.
Then it was Carpenter's turn to go deep. Minor left a fastball out over the plate and his counterpart, swinging late but making good contact, sent a drive to right that just cleared the wall over a leaping Heyward. Carpenter made an extremely slow trot around the bases, thoroughly savoring the moment.
It didn't last.
NOTES: RHP Jake Westbrook will have an extra mouth to feed when he starts Saturday for the Cardinals. His wife, Heather, delivered the couple's third child on Thursday, a girl named Harper. ... Braves hitting coach Terry Pendleton was ejected by first-base umpire Jim Reynolds in the third inning for arguing over a checked swing by Albert Pujols. Reynolds ruled that Pujols didn't go around, Pendleton began shouting from the dugout and the umpire quickly gave him the heave. The ump even waved at Pendleton and mouthed, "Bye, bye." ... OF Skip Schumaker didn't start for St. Louis despite hitting a homer in the series opener. Russa didn't want to use the left-handed hitter against the Braves' lefty starter. Schumaker will be in the lineup for the final two games of the series against RHPs Tommy Hanson and Tim Hudson.
[Associated Press;
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