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In doubles, French Open champions Andrea Hlavackova and Lucie Hradecka will play the Italian pair of Errani and Roberta Vinci.
In Moscow, Anastasia Pavlyuchenkova of Russia takes on Jelena Jankovic of Serbia in opening singles. Two-time Grand Slam champion Svetlana Kuznetsova will face former French Open champion Ana Ivanovic in the second match.
Serbia has reached the semifinals of the tournament for the first time and features two former No. 1 players. Russia, a four-time champion, has beaten Serbia in all three of their previous matches, but is without its two top players: Maria Sharapova and Vera Zvonareva.
In doubles, Russians Maria Kirilenko and Elena Vesnina will face Bojana Janovski and Aleksandra Krunic.
"It's going to be a historic moment for us." Jankovic said. "Hopefully, we could make it into the final. It's been a long way to come up to this stage. It will be a tough match. We are playing against Russia and in Russia."
Copyright 2012 The Associated Press. All rights reserved. This material may not be published, broadcast, rewritten or redistributed.
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