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The Nationals scored in the first on LaRoche's RBI single.
Washington equaled a club mark by hitting three home runs in the third off Chris Volstad (2-10). Roger Bernadina led off with his fourth of the season. Harper followed with his 16th. Zimmerman singled and LaRoche hit his 28th homer.
Harper hit his 17th with one out in the sixth against Michael Bowden.
Ian Desmond and Espinosa hit back-to-back home runs to start the seventh off Blake Parker.
Volstad allowed five runs and nine hits in five innings. He had won his previous two starts.
"That's a tough lineup and he couldn't keep the ball down today, that's the bottom line," Sveum said.
Volstad was wary of facing the Nationals, who scored eight or more runs in three of four games against St. Louis.
"They put up runs all over the place against them, too," Volstad said. "They're a hot team. A good team and they're hot. It's a tough combo, but you've still got to go out there and make good pitches."
NOTES: Harper's 17 home runs are the third-most by a teenager. Only Tony Conigliaro with 24 and Ott with 18 hit more. ... Vitters is in an 0-for-25 skid. ... Chicago is 17-51 on the road. ... Nationals RHP Jordan Zimmermann (9-8, 3.01 ERA) will face Chicago RHP Justin Germano (2-5, 6.30 ERA) on Thursday.
Copyright 2012 The Associated Press. All rights reserved. This material may not be published, broadcast, rewritten or redistributed.
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