The walkouts were the first held in support of a nationwide pact
since 1980 and target plants with a combined 10 percent of U.S.
refining capacity.
Talks broke down against a backdrop of plunging crude prices, which
have fallen by half since June, prompting oil companies to cut
spending.
The United Steelworkers union (USW) said Royal Dutch Shell Plc, the
lead industry negotiator, halted negotiations early on Sunday after
the union rejected a fifth proposal from the company. Shell said it
would like to restart talks.
Shell activated a strike contingency plan at its joint venture
refinery and chemical plant in Deer Park, Texas, to keep operating
normally.
Other companies said they called on trained managers as replacement
workers, so the strikes are not expected to cause gasoline prices to
surge.
Still, oil prices fell early on Monday in Asia, with traders citing
the strikes, which could potentially dent demand, and strong price
gains last week.
Brent crude oil futures were trading at $51.63 a barrel at 0130 GMT,
down $1.36, while U.S. West Texas Intermediate futures had dropped
$1.37 to $46.87 a barrel.
Tesoro Corp said management was operating its refinery in Carson,
California, and that managers would take over from union workers at
its plant in Anacortes, Washington, in the next 24-48 hours. It said
its Martinez, California, refinery, which was undergoing maintenance
work, would be shut down.
Besides Shell and Tesoro, the USW said strikes were called at three
plants belonging to Marathon Petroleum in Texas and Kentucky, and
LyondellBasell's plant near Houston. At least two of the plants on
the list have a history of deadly accidents.
The USW said all other refineries it represents - including Exxon
Mobil Corp's refinery in Beaumont, Texas - would operate under
rolling 24-hour contract extensions.
The expiring three-year national contract covers about 30,000 hourly
workers at plants that together have two-thirds of U.S. refining
capacity.
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The latest rejected proposal was the fifth turned down since
negotiations for a new three-year agreement began on Jan. 21.
The USW is seeking annual pay raises double the size of those in the
last agreement. It also wants work that has been given in the past
to non-union contractors to start going to USW members, a tighter
policy to prevent workplace fatigue, and reductions in members'
out-of-pocket payments for healthcare.
Gene Oliver, president of the union chapter at LyondellBasell, said
the company brought 10 issues to the table and did not want to
discuss all of the 36 points the union raised.
"They were unwilling to work on the issues," he said.
Independent refiners, such as Valero Energy Corp, have made big
profits recently by tapping cheap crudes from the U.S. shale
revolution, while refining units at integrated companies such as
Exxon have provided a cushion against low prices hurting upstream
operations.
But the drop in oil prices since last summer, when they were above
$100 per barrel, has hurt the union's hand, analysts said.
(Writing by Terry Wade; Editing by Eric Walsh)
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