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Larcher de Brito, meanwhile, had advanced to the second round by beating Argentina's Gisela Dulko 7-5, 7-6 (1) on Tuesday. That's after she won three qualifying matches to reach the main draw.
"It was almost an upset but I still have a lot of years ahead of me and a lot of experience to gain, a lot of tennis to play," said Larcher de Brito, who hopes to get into the U.S. Open though is currently an alternate. "She just has all the power, all the experience. She's been there for many years now. I'm just coming (up) now and hopefully I'll do well."
Venus Williams is not playing in this event at Stanford.
Earlier Wednesday, Ai Sugiyama ousted fourth-seeded Daniela Hantuchova of Slovakia 6-3, 6-1 to advance to the quarterfinals.
The unseeded Sugiyama, from Japan, fell behind 3-0 in the first set then won the next nine games before Hantuchova held serve to make it 3-1 in the second set. Sugiyama needed three sets to beat wild-card entry Alexa Glatch in the first round.
Hantuchova has been dealing with a stress fracture in her right heel since May and Wimbledon was her first tournament since April. She lost in the second round of Wimbledon to Kleybanova.
Sugiyama will face Slovakia's Dominika Cibulkova, a 6-2, 6-3 second-round winner over Kateryna Bondarenko of the Ukraine on Wednesday.
Second-seeded Anna Chakvetadze of Russia beat Shahar Peer of Israel 6-3, 6-4. Chakvetadze lost the first game of each set and trailed 4-3 in the second before winning the final three games.
She will play the winner of Thursday's second-round match between No. 6 Marion Bartoli of France and England's Anne Keothavong.
[Associated Press;
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