Tim Hudson (10-7) gave up nine hits and five runs in 6 2-3 innings, but the big hits by McCann and rookie Brent Lillibridge helped Hudson improve to 8-1 in 12 career starts against Washington. Hudson is 7-0 in his last eight starts against the Nationals. He began the night with a 1.13 career ERA against Washington.
The Nationals, trailing 7-5, scored a run in the ninth against Mike Gonzalez. Pinch-hitter Felipe Lopez hit a one-out single and moved to third on a double to right by Willie Harris. Lopez scored on Paul Lo Duca's grounder to second, sending Harris to third.
Gonzalez hit Christian Guzman with a pitch but earned his fourth save when Austin Kearns flied out to right field.
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Lillibridge gave the Braves a 2-0 lead in the second with a two-run double. Lillibridge, making his fourth straight start for Yunel Escobar (sore left shoulder), was 2-for-4 and has four extra-base hits in his last three games.
Lillibridge added a single in the sixth and scored on Kelly Johnson's single.
The Nationals tied it with three hits in the third. Kory Casto led off with a double over Mark Kotsay in center field and scored on Ryan Langerhans' single. With two outs, Lo Duca drove in Langerhans with another single up the middle.
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The Braves scored four in the third. McCann's bases-loaded double to right drove in Gregor Blanco, Chipper Jones and Mark Teixeira. Blanco and Teixeira reached on walks. Kotsay added a single to drive in McCann for a 6-2 lead.
Tim Redding (7-4) gave up six runs on six hits and three walks in four innings, matching his shortest start of the season. The six earned runs allowed matched his season high.