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Pittsburgh had a pair of hits in the 16th but Molina threw out Jose Tabata trying to steal and reliever Joe Kelly induced McCutchen to ground out to end the inning.
Reliever Edward Mujica got Neil Walker to ground into a double play to end the 11th. Kelly allowed four hits and one run in 5 2-3 innings of his first relief appearance.
Carlos Beltran put St. Louis in front with a two-run double in the fourth, and also stole three bases, tying a career high. Beltran leads the NL with 85 RBIs.
"Twenty innings or nine innings, a loss is a loss," Beltran said. "We had the opportunities. It just didn't happen."
Pittsburgh starter Jeff Karstens gave up two runs and two hits over seven innings. He struck four and walked one.
The Pirates scored twice in the sixth to tie it on a pair of infield singles and Garcia's throwing error. Clint Barmes reached on an infield hit and Garcia mishandled a bunt attempt by Karstens. Josh Harrison drove in Barmes with a sacrifice fly and McCutchen followed with an infield single.
Chris Resop led the Pirates' bullpen effort with three scoreless innings. Kevin Correia and Jared Hughes added two scoreless innings each.
Hurdle said he has yet to select a starting pitcher to replace Rodriguez on Monday.
"I'll come up with something tomorrow," he said.
NOTES: St. Louis 1B Allen Craig extended his hitting streak to nine games with a single in the fourth inning. .. Jon Jay snapped an 0-for-14 skid with a two-out single in the 13th. .... Garcia's 10 strikeouts are the most by a St. Louis left-hander since Mark Mulder had 12 on May 9, 2005, against Los Angeles. ... The Cardinals sent RHP Trevor Rosenthal to Triple-A Memphis prior to the game to make room for Garcia. .... St. Louis plays host to Houston in a three-game set beginning Tuesday. Adam Wainwright (11-10, 3.87) will face Lucas Harrell (10-8, 3.81) in the series opener. Wainwright drew a walk as a pinch hitter Sunday. ... Pittsburgh closes out a six-game road trip with three at San Diego starting Monday. ... Pirates 2B Neil Walker did not start for the fourth successive game with a dislocated pinky on his right hand. He later pinch hit. ... Molina grounded out to second to finish a 14-pitch at-bat in the fourth.
Copyright 2012 The Associated Press. All rights reserved. This material may not be published, broadcast, rewritten or redistributed.
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